Guide

What is oxygen gas used for? Industrial medical and process uses with the purity each one needs

Oxygen gas is used wherever combustion or oxidation must run faster or hotter than air allows: basic-oxygen steelmaking, oxy-acetylene cutting at 3,100 °C, medical oxygen therapy, ozone and activated-sludge water treatment, glass and non-ferrous furnaces. IS 309:2023 sets 3 industrial grades from 99.0 to 99.95 %; medical oxygen is governed by the Indian Pharmacopoeia.

A KIGL gas plant, with branded columns and storage vessels against open sky
Industrial grades
IS 309:2023 Grade 1
Medical oxygen
≥ 99.0 % v/v
Oxy-acetylene flame
About 3
Oxygen in air
20.95 % by volume; pure oxygen is 1.105 times as dense as air
Cylinder colour
Industrial: Graphite Black RAL 9011 throughout. Medical: black body

Oxygen is bought for one property: it makes oxidation faster. Air is 20.95 % oxygen by volume and the other 79 % is dead weight that must be heated, pumped and vented. Replace it with oxygen at 99.5 % and a furnace runs hotter, a cutting jet burns steel instead of merely heating it, a patient receives five times the partial pressure of oxygen per breath, and an aeration tank dissolves oxygen about five times as fast, so it can treat more organic load in the same volume. Every use below is a version of that one fact, and the only real variable is how pure the oxygen must be.

How pure does oxygen need to be?

IS 309:2023, the Indian specification for compressed and liquid oxygen, replaced the old single figure with three grades. The grade designation follows the industry "N" convention: the first digit is the number of nines, the decimal is the next digit, so N2.5 means 99.5 % and N3.5 means 99.95 %.

Characteristic Grade 1 (N3.5) Grade 2 (N2.5) Grade 3 (N2.0)
Oxygen, % v/v, min 99.95 99.5 99.0
Nitrogen, ppm max 100 100 —
Water vapour, ppm max 1.5 2.0 67
Carbon dioxide, ppm max 0.2 0.5 2.0
Carbon monoxide, ppm max 0.2 0.5 3.0
Hydrocarbons, ppm max 10 20 50
Intended use (IS 309 cl 4) Calibration, impurity-sensitive work Laser-cutting assist gas; liquid oxygen Welding and metallurgical work

Source: IS 309:2023 Table 1 and clause 4. Note 1 to the table adds that oxygen made by air separation shall not normally contain CO, CO₂ or hydrocarbons, so for air-separation product these are tested only by agreement between buyer and seller. KIGL industrial oxygen is supplied to Grade 2 (N2.5), minimum 99.5 %.

Medical oxygen sits outside this table altogether. IS 309 clause 1 excludes "oxygen for medical or inhalation purposes"; the governing document is the Indian Pharmacopoeia monograph, which asks for not less than 99.0 % v/v oxygen with carbon dioxide at 300 ppm maximum and carbon monoxide at 5 ppm maximum, filled under a drug licence. The difference is explained on industrial vs medical oxygen.

Steelmaking: the largest use

The basic oxygen furnace (BOF) is a pear-shaped vessel into which a water-cooled lance blows near-pure oxygen at supersonic velocity onto molten pig iron. Carbon in the iron burns to CO and CO₂, silicon, manganese and phosphorus go into the slag, and the heat of those reactions alone raises the melt from about 1,350 °C to tapping temperature with no external fuel. Electric arc furnaces use oxygen differently, through lances and oxy-fuel burners that speed the melt-down of scrap and refine the bath, but the gas is the same.

The volumes are large enough that integrated steelworks typically run their own cryogenic air separation units and pipe oxygen to the converter shop. Merchant oxygen in cylinders serves the foundries, re-rollers and fabricators around the works rather than the converter itself. Oxygen is also injected into blast-furnace blast and into cupolas: enriching the blast from 21 % to 23 or 24 % oxygen raises the flame temperature in the raceway and lets the furnace burn more injected coal per tonne of hot metal.

Cutting and welding

Oxy-fuel cutting is the use most buyers meet first, and it is widely misunderstood. The flame does not cut the steel. A preheat flame of acetylene and oxygen brings a spot on the plate to its ignition temperature, around 870 to 900 °C for mild steel, and then a separate jet of pure oxygen burns the iron to iron oxide. The reaction Fe + ½O₂ → FeO is strongly exothermic and supplies most of the heat that keeps the cut moving; the preheat flame only sustains the ignition temperature at the top of the kerf. This is why cutting oxygen purity matters so much more than preheat gas purity: nitrogen or argon in the jet dilutes the reaction, slows the cut and leaves a rougher, more adherent dross. The standard the trade works to is 99.5 % minimum, IS 309 Grade 2, and the full mechanism is on the oxy-acetylene welding and cutting page.

For the preheat and for welding, oxygen is paired with acetylene because the oxy-acetylene flame, at about 3,100 °C, is the hottest of the industrial fuel gases. The stoichiometric reaction 2C₂H₂ + 5O₂ → 4CO₂ + 2H₂O needs 2.5 volumes of oxygen per volume of acetylene, but a neutral welding flame is set at roughly 1:1 at the torch and draws the rest from the surrounding air in the outer envelope. A plate-cutting torch at 25 mm thickness is a modest consumer; a profile-cutting bay running several torches on a shift is the kind of load for which fabricators move from cylinders to a manifold or to an oxygen pipeline, and the cleanliness rules for that pipework are on oxygen pipeline cleanliness.

Related uses in the same workshop: oxy-fuel brazing and heating for bending, flame gouging, scarfing of billets in steel mills, and flame hardening of gears and ways.

Medical and respiratory oxygen

Oxygen therapy raises the partial pressure of oxygen in the lungs. Air at sea level delivers about 21 kPa of oxygen partial pressure; breathing pure oxygen through a mask delivers up to five times that. Hospitals take it in three forms: cylinders of medical oxygen at 99.0 % or better to the Pharmacopoeia monograph, bulk liquid oxygen vaporised into a medical gas pipeline system, and on-site pressure-swing adsorption plants.

PSA plants produce 90 to 96 % oxygen with the balance argon and nitrogen, and the Pharmacopoeia covers this under a separate "Oxygen 93 per cent" monograph. The distinction matters when reading a tender: a hospital specifying "IP oxygen" for cylinders is asking for the 99.0 % product, while one installing a PSA oxygen plant is working to the 93 % monograph. How the adsorption process reaches that purity, and why it does not go higher without a second stage, is on how PSA oxygen generation works.

The cylinder colour difference is a legal one. Industrial oxygen cylinders are Graphite Black RAL 9011 all over under IS 4379:2021; medical cylinders are black with a white RAL 9003 shoulder under IS 3933:2021. A black cylinder with a white shoulder in a fabrication shop, or a plain black one on a ward, is a compliance failure.

Water and effluent treatment

Ozone is the strongest disinfectant in routine use for drinking water, bottled water and swimming pools, and it is generated by passing oxygen through a silent electrical discharge. Feeding the generator with oxygen rather than dried air roughly doubles the ozone concentration achievable per unit of power and removes the nitrogen oxides that air-fed generators produce. Oxygen is also dosed directly into aeration tanks at sewage works and at pulp, dairy, brewery and chemical plants whose effluent carries a high biochemical oxygen demand. The driving force for dissolving oxygen is its partial pressure, so pure oxygen at the same pressure transfers about five times as fast as air into the same water, which lets an overloaded tank meet its discharge consent without being rebuilt. Fish farms and hatcheries use the same principle to hold higher stocking densities.

Glass, non-ferrous metals and chemicals

Oxy-fuel combustion, in which natural gas or oil burns with oxygen instead of air, is standard in glass melting furnaces, in copper and lead smelting and in cement kilns. Taking the nitrogen out of the flame raises its temperature, cuts the volume of flue gas that must be heated and exhausted, and largely eliminates thermal NOx. In glassworks the gain is cleaner melt and lower fuel per tonne; in secondary aluminium and copper it is faster melting in rotary furnaces. The chemical industry uses oxygen as a feedstock: ethylene oxide, vinyl acetate, titanium dioxide by the chloride route, and partial oxidation of hydrocarbons to synthesis gas all run on oxygen from dedicated air separation units.

Rules that matter

Smaller but demanding uses

  • Laser cutting of carbon steel uses oxygen as the assist gas and is the named application for IS 309 Grade 2; water vapour and hydrocarbons at ppm levels affect edge quality.
  • Rocket propulsion uses liquid oxygen as oxidiser; the cryogenic upper stages of Indian Space Research Organisation launch vehicles burn liquid oxygen with liquid hydrogen.
  • Aquaculture, hyperbaric medicine, diving decompression, aircraft breathing systems (excluded from IS 309 as "aviation oxygen" and governed separately).
  • Semiconductor and optical-fibre manufacture use Grade 1 oxygen for oxidation steps where parts-per-million contaminants spoil the product.

Rules that matter

What this means for a buyer

  • State the grade, not just the purity: "IS 309:2023 Grade 2 (N2.5)" is a complete specification; "99.5 % oxygen" is not, because the impurity limits differ between grades.
  • Do not use industrial oxygen for breathing, and do not accept a medical cylinder without a white shoulder, a drug-licence batch number and the oxygen safety data sheet.
  • Cutting quality problems that appear as slow cuts and sticky dross are usually oxygen purity or oxygen pressure, not the fuel gas.
  • Oxygen is an oxidiser, not a fuel, and the enrichment hazard begins at 23.5 % in the workplace atmosphere; see oxygen enrichment and deficiency and oxygen safety data explained.
  • Properties, cylinder pressures and the liquid-to-gas expansion ratio are on the oxygen technical data page.

What is oxygen gas used — frequently asked questions

What is the biggest industrial use of oxygen gas?

Steelmaking. The basic oxygen furnace blows near-pure oxygen through a water-cooled lance into molten iron to burn out carbon, silicon and phosphorus; electric arc furnaces use oxygen lances and burners for the same job. Together they take more oxygen than every other use combined, which is why large steelworks run their own air separation units and pipe oxygen directly to the shop.

What purity of oxygen is needed for gas cutting?

Welding-grade oxygen of at least 99.5 % v/v, which is IS 309:2023 Grade 2 (N2.5). Cutting is an oxidation reaction of iron, not just a flame, so impurities in the cutting jet slow the cut and roughen the kerf. Grade 3 at 99.0 % is acceptable for heating and some welding duties but is not what a cutting torch is designed around.

Is medical oxygen the same as industrial oxygen?

No, not in law and not in control. IS 309:2023 clause 1 expressly excludes medical oxygen; it is governed by the Indian Pharmacopoeia monograph (minimum 99.0 % v/v, carbon dioxide 300 ppm max, carbon monoxide 5 ppm max) and filled under a drug licence with batch records. The gas may come from the same air separation plant; the cylinder, its white shoulder, the testing and the paperwork are different.

Can PSA oxygen be used in hospitals?

Yes, as the Indian Pharmacopoeia "Oxygen 93 per cent" grade, which covers pressure-swing adsorption product at 90 to 96 % oxygen with the balance argon and nitrogen. It is piped directly to wards from an on-site PSA plant and is not the same monograph as cylinder oxygen at 99.0 %. Check which grade a tender specifies before quoting.

Why is oxygen used in water treatment?

Two reasons. Ozone for disinfection is made by passing oxygen, not air, through a corona discharge, which roughly doubles the ozone yield per unit of power. And activated-sludge plants under oxygen load can treat more biochemical oxygen demand in the same tank volume because the transfer driving force is about five times that of air.

How much oxygen does a cylinder hold?

A 46.7 litre water-capacity cylinder at 150 bar holds about 7.0 m³ of oxygen on an ideal-gas basis at 15 °C, and about 5 % more once the compressibility of oxygen at that pressure is allowed for. IS 309:2023 clause 6.2 states cylinder contents at 27 °C and 760 mm Hg, which adds a further 4 % to the quoted figure.

What are the hazards of using oxygen?

Oxygen does not burn, but it makes everything else burn faster and at lower ignition energy. Oil or grease in oxygen service can ignite on adiabatic compression, clothing soaked in oxygen-enriched air burns violently, and an atmosphere above about 23.5 % oxygen is treated as enriched by EIGA. Use oxygen-clean fittings and never use oxygen to ventilate, cool or blow down.

Does oxygen purity matter for medical use more than industrial?

The medical monograph is actually looser on the oxygen assay (99.0 % against 99.5 % for welding grade) but much tighter on what the balance may contain: carbon monoxide at 5 ppm and carbon dioxide at 300 ppm are patient-safety limits. Industrial Grade 2 allows 0.5 ppm CO but has no concern for odour, taste or breathing comfort.

References

  1. Bureau of Indian Standards. (2021). and IS 3933:2021 cylinder colour identification (IS 4379:2021, Second Revision).
  2. Bureau of Indian Standards. (2023). Oxygen, compressed gas and liquid — Specification (IS 309:2023, Fifth Revision).
  3. EIGA — oxygen enrichment and oxygen safety documents
  4. Indian Pharmacopoeia Commission. (n.d.). Indian Pharmacopoeia: Oxygen and Oxygen 93 per cent monographs.
  5. Linstrom, P. J., & Mallard, W. G. (Eds.). (n.d.). NIST Chemistry WebBook (NIST Standard Reference Database 69). National Institute of Standards and Technology. [oxygen thermophysical properties] https://webbook.nist.gov/cgi/cbook.cgi?ID=C7782447

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