Guide

Argon technical data sheet: physical properties IS 5760 status, purity grades and cylinder pressure

Argon (Ar, 39.948 g/mol) boils at −185.85 °C, has a gas density of 1.784 kg/m³ at 0 °C and is 1.38 times as heavy as air. Its critical point is −122.46 °C and 48.63 bar. Welding argon is 99.99 % (ISO 14175 I1) and instrument argon 99.999 %; IS 5760 is the Indian specification.

Safety data sheet

Boiling point
−185.85 °C
Critical point
−122.46 °C
Gas density
1.784 kg/m³ at 0 °C
Liquid expansion
Liquid at 1
Welding grade
ISO 14175 Group I1: argon

Argon is a noble gas that makes up 0.934 % of air by volume and is recovered as a by-product of cryogenic oxygen and nitrogen production. Its boiling point sits between those of nitrogen and oxygen, which is why it is drawn from the middle of the air separation column and purified separately. It is a permanent gas with a critical temperature of −122.46 °C, so it is sold by pressure in cylinders and as liquid in bulk. The physical figures below are from the NIST Chemistry WebBook; the standards position is from the Bureau of Indian Standards catalogue. KIGL argon is supplied in two grades published as KIGL specifications.

Physical properties

Property Value Source
Symbol, molar mass Ar, 39.948 g/mol NIST
Boiling point at 1.013 bar −185.85 °C (87.30 K) NIST
Triple point −189.34 °C (83.81 K), 0.689 bar NIST
Critical temperature −122.46 °C (150.69 K) NIST
Critical pressure 48.63 bar NIST
Gas density, 0 °C, 1 atm 1.784 kg/m³ NIST
Gas density, 15 °C, 1 atm 1.690 kg/m³ NIST
Relative density to air 1.38 NIST
Liquid density at boiling point 1,395 kg/m³ NIST
Liquid to gas expansion about 825 at 15 °C; about 840 at 21 °C Computed from NIST densities
Latent heat of vaporisation about 161 kJ/kg NIST
Specific heat Cp, gas, 25 °C about 0.520 kJ/kg·K NIST
Ratio of specific heats Cp/Cv 1.67 (monatomic) NIST
Thermal conductivity, gas, 25 °C about 0.0177 W/m·K NIST
Viscosity, gas, 25 °C about 22.6 µPa·s NIST
First ionisation energy 15.76 eV NIST Atomic Spectra Database
Content of dry air 0.934 % by volume Standard atmosphere
UN number 1006 compressed; 1951 refrigerated liquid IS 4379:2021 Table 1; UN list

Several of these numbers explain argon's uses directly. A ratio of specific heats of 1.67, against 1.40 for nitrogen and oxygen, is the mark of a monatomic gas with no internal rotation or vibration to store energy. A thermal conductivity about two thirds that of air is why it is used to fill insulating glass. An ionisation energy of 15.76 eV, against 24.59 eV for helium, is why the argon arc strikes and holds at low current. And a density 1.38 times air is why it shields a weld pool well and why it collects in low places when it leaks.

Grades and the standards position

The Indian specification is IS 5760, Argon, compressed and liquid, under the CHD 06 Industrial Gases committee. Two editions are live in the BIS catalogue: the 1998 second revision, reaffirmed February 2021 with one amendment, and a third revision published in 2026. IS 309:2023 notes that it harmonised its liquid-oxygen provisions with IS 5760:1998, which is the only clause-level trace of IS 5760 in the standards KIGL holds. Because the text of neither edition is held, KIGL does not quote an IS 5760 grade limit and publishes its argon grades as its own specifications; the corrected product specifications confirm that this is the right treatment.

Internationally, ISO 14175 defines the welding grade, classifying argon as Group I1 with a minimum purity of 99.99 %. The purer grades follow supplier convention, using the same "N" or numeric notation as IS 309 and IS 1747 (4.0 = 99.99 %, 5.0 = 99.999 %).

Grade (market notation) Argon, % min Typical oxygen, ppm max Typical moisture, ppm max Typical use
4.0 welding grade 99.99 about 10 about 10 TIG, MIG, plasma, purging, AOD, heat treatment
4.8 99.998 about 3 about 5 Titanium, zirconium and nickel-alloy welding
5.0 high purity 99.999 about 2 about 3 GC carrier, ICP, glove boxes, lamp filling
6.0 research grade 99.9999 about 0.5 about 0.5 Semiconductor, analytical calibration

Purity minima are the grade definitions; the impurity columns are typical market values, not IS 5760 figures, and are shown to indicate scale. KIGL's own limits are on the argon product page, and the regulatory picture is on argon standards.

Cylinder and pressure data

Argon is filled into seamless steel cylinders to IS 7285 (Part 1):2018 or (Part 2):2017, with IS 3224:2021 valves and a right-hand outlet thread. As a permanent gas it falls under IS 8775:1978, which fixes the filling pressure at 15 °C and checks the developed pressure at 65 °C. Its compressibility factor at 150 bar and 15 °C is about 0.93 (NIST), so a cylinder holds slightly more argon than the ideal-gas calculation suggests.

Water capacity Fill pressure at 15 °C Ideal content, 15 °C Approximate real content, 15 °C Mass of argon
46.7 L 150 bar 6.96 m³ about 7.4 m³ about 12.5 kg
46.7 L 200 bar 9.26 m³ about 9.8 m³ about 16.6 kg
10 L 150 bar 1.49 m³ about 1.6 m³ about 2.7 kg

Mass is real content at 15 °C times 1.690 kg/m³. These are worked examples; the method is on gas cylinder sizes and contents in India. Pressure rises about 0.4 % per °C, so a welding cylinder left in the sun at 50 °C reads about 15 % above its 15 °C fill. A welder using 10 to 15 litres per minute through a TIG torch empties a 7.4 m³ cylinder in roughly 8 to 12 hours of arc-on time; heavy users move to liquid argon or a manifold.

Under IS 4379:2021 the cylinder is peacock blue shade 103 throughout. Argon-based mixtures add a band: light Brunswick green for argon-CO₂, graphite black for argon-oxygen, and a French grey band with a peacock blue shoulder for argon-nitrogen (Table 12). Under GCR 2016 rule 44(b)(ii), up to 200 cylinders of a non-flammable non-toxic gas may be held without a storage licence.

Liquid argon

Liquid argon at 1,395 kg/m³ is the densest of the common cryogens and expands about 840 times to gas at 21 °C. Its liquid range at atmospheric pressure is very narrow: it boils at 87.30 K and its triple point is 83.81 K at 0.689 bar. A bulk tank or line depressurised below about 0.7 bar absolute can therefore freeze solid argon in valves and vaporisers, and vacuum on a liquid argon line is avoided. Bulk vessels are licensed under the SMPV (Unfired) Rules 2016; transportable vacuum-insulated vessels up to 1,000 litres are covered by IS 18719 (Parts 1 and 2):2024.

Rules that matter

Handling notes

Argon technical data sheet — frequently asked questions

What is the boiling point of argon?

−185.85 °C (87.30 K) at atmospheric pressure, from the NIST Chemistry WebBook. Argon's triple point is −189.34 °C at 0.689 bar, only 3.5 K below the boiling point and at a pressure close to atmospheric, so liquid argon exists over a very narrow temperature band at 1 atm and can freeze in lines if the pressure falls.

How much heavier than air is argon?

1.38 times, from a gas density of 1.784 kg/m³ at 0 °C against 1.293 for air. Argon released at room temperature settles into pits, trenches, tank bottoms and the inside of pipes and vessels being welded, and stays there unless ventilated. Cold vapour from liquid argon is denser still. That is why welding bays and purged spaces need oxygen monitoring at low level.

What purity of argon is used for welding?

99.99 %, the minimum for ISO 14175 Group I1, with oxygen and moisture each in the low parts per million. Titanium, zirconium and some nickel alloys are specified at 99.998 % or better. Gas chromatography, ICP spectrometry and glove boxes use 99.999 % (5.0) or purer, with oxygen, water and hydrocarbons at or below 1 to 2 ppm.

Is there an Indian standard for argon?

Yes: IS 5760, Argon, compressed and liquid. The Bureau of Indian Standards lists the 1998 second revision, reaffirmed February 2021 with one amendment, and a third revision published in 2026. KIGL does not yet hold the text of either edition, so its argon grades are published as KIGL specifications rather than as IS 5760 grades.

What pressure are argon cylinders filled to?

Typically 150 to 200 bar at 15 °C in seamless steel cylinders to IS 7285. IS 8775:1978 is the standard that ties the filling pressure at 15 °C to the developed pressure at 65 °C for permanent gases including argon. A 46.7 litre cylinder at 150 bar holds about 7.4 m³ at 15 °C, slightly more than ideal because argon's compressibility factor is below 1.

Which colour code does IS 4379 give argon cylinders?

Peacock blue, shade 103, with the shoulder in the ground colour and no band, under IS 4379:2021 Table 7. An argon-CO₂ welding mixture is peacock blue with a light Brunswick green band; argon-oxygen is peacock blue with a graphite black band; argon-nitrogen has a peacock blue shoulder and a French grey band (Table 12).

Why is argon used instead of nitrogen as a shield?

Nitrogen reacts with molten steel, titanium, aluminium and magnesium to form nitrides and is absorbed into weld metal. Argon, a noble gas, reacts with nothing under any industrial condition, and its ionisation energy of 15.76 eV gives a stable, easily struck arc. Nitrogen is used where it is chemically harmless because it is far cheaper.

References

  1. Bureau of Indian Standards. (1978). Filling pressure and corresponding developed pressure for permanent gases contained in cylinders (IS 8775:1978).
  2. Bureau of Indian Standards. (2021). Identification of the contents of industrial gas cylinders (IS 4379:2021, Second Revision).
  3. EIGA — inert gas asphyxiation documents
  4. International Organization for Standardization. (2008). Welding consumables — Gases and gas mixtures for fusion welding and allied processes (ISO 14175:2008).
  5. IS 5760 Argon, compressed and liquid — Specification
  6. Linstrom, P. J., & Mallard, W. G. (Eds.). (n.d.). NIST Chemistry WebBook (NIST Standard Reference Database 69). National Institute of Standards and Technology. [argon thermophysical properties] https://webbook.nist.gov/cgi/cbook.cgi?ID=C7440371
  7. NIST Atomic Spectra Database — ionisation energies https://www.nist.gov/pml/atomic-spectra-database

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