Guide

Helium technical data: density boiling point, compressibility, purity grades and the gas in balloons

Helium (He, 4.0026 g/mol) is an inert, non-flammable gas of 0.1785 kg/m³ at 0 °C and 1 atm, seven times lighter than air. It boils at −268.9 °C (4.2 K), the lowest of any substance, and is sold in grades from balloon gas to 6.0 (99.9999 %). India produces none; it is imported.

Safety data sheet

Gas density
0.1785 kg/m³ at 0 °C and 1.01325 bar; 0.1692 kg/m³ at 15 °C; relative density about 0.14
Boiling and critical points
Boils at −268.93 °C
Speed of sound and heat
About 1
Compressed contents
At 150 bar and 15 °C one litre of water capacity holds 23.4 g
Indian identification
Middle brown

Helium is the second-lightest element and the most inert: a single atom, molar mass 4.0026 g/mol, a gas density of 0.1785 kg/m³ at 0 °C and a boiling point of 4.22 K that no other substance comes near. Those properties explain all of its uses, from the balloon at a wedding to the liquid that keeps an MRI magnet superconducting. This page sets out helium's physical data from the NIST Chemistry WebBook, how it behaves in a cylinder, how its purity grades are named, and where it comes from. Helium is not produced in India; KIGL supplies it from licensed producers.

Helium properties table

Property Value Conditions Source
Symbol and form He, monatomic — NIST Chemistry WebBook
CAS number 7440-59-7 — NIST Chemistry WebBook
Molar mass 4.0026 g/mol — NIST Chemistry WebBook
Gas density 0.1785 kg/m³ 0 °C, 1.01325 bar NIST Chemistry WebBook
Gas density 0.1692 kg/m³ 15 °C, 1.01325 bar NIST Chemistry WebBook
Gas density 0.1663 kg/m³ 20 °C, 1.01325 bar NIST Chemistry WebBook
Relative density about 0.14 (air = 1) 0 °C NIST Chemistry WebBook
Normal boiling point −268.93 °C (4.22 K) 1 atm NIST Chemistry WebBook
Liquid density about 125 kg/m³ at the boiling point NIST Chemistry WebBook
Critical temperature −268.0 °C (5.2 K) — NIST Chemistry WebBook
Critical pressure 2.3 bar — NIST Chemistry WebBook
Specific heat, Cp 5.19 kJ/kg·K 0–20 °C, 1 atm NIST Chemistry WebBook
Ratio of specific heats 1.67 20 °C, 1 atm NIST Chemistry WebBook
Speed of sound about 1,008 m/s 20 °C, 1 atm NIST Chemistry WebBook
Thermal conductivity 0.154 W/m·K 20 °C, 1 atm NIST Chemistry WebBook
Viscosity 19.6 µPa·s 20 °C, 1 atm NIST Chemistry WebBook
Flammability None; does not burn or support combustion — UN Model Regulations (Class 2.2)
Transport identity UN 1046 compressed; UN 1963 refrigerated liquid — IS 4379:2021 Table 1; UN Model Regulations
Cylinder colour Middle brown (411) throughout — IS 4379:2021 Table 7

Read three rows together. The density, one-seventh that of air, is why helium lifts and why it collects under ceilings when it leaks. The speed of sound, about 1,008 m/s at 20 °C against 343 m/s in air, is why the voice changes when someone breathes it; that is a sign the lungs hold no oxygen, as helium safety data explained sets out. The ratio of specific heats, 1.67, is the textbook value for a monatomic gas; helium has no molecular rotation or vibration to store heat, which makes it a near-ideal gas at room temperature.

What fills a balloon, and why

Lifting medium Density at 15 °C, 1 atm Approximate gross lift per m³ Flammable
Helium 0.169 kg/m³ (NIST) about 1.05 kg No
Hydrogen 0.085 kg/m³ (NIST) about 1.14 kg Yes, 4–75 % in air
Air, for reference about 1.225 kg/m³ 0 —

The lift of a gas is the mass of air it displaces minus its own mass. Hydrogen lifts about 8 % more than helium for the same volume, but it burns over a 4 to 75 % range in air, so party, display and promotional balloons use helium. The gas sold for balloons is usually a lower purity than laboratory helium, because a few per cent of air makes little difference to lift. It is still an asphyxiant: inhaling it, from a balloon or a cylinder, replaces the oxygen in the lungs. The lift figures above match those on uses of helium gas.

How helium compresses in a cylinder

Helium is delivered as a compressed gas, normally in seamless steel cylinders, because its critical temperature of 5.2 K means it can never be liquefied by pressure at ambient temperature. Like hydrogen, it is slightly less compressible than an ideal gas at cylinder pressures. NIST gives these densities at 15 °C:

Fill pressure at 15 °C Density Gas at 1 atm and 15 °C per litre of water capacity Ideal-gas figure Compressibility, Z
150 bar 23.35 kg/m³ about 138 litres 148 litres about 1.07
200 bar 30.46 kg/m³ about 180 litres 197 litres about 1.10

So multiplying water capacity by gauge pressure in bar (150 or 200 litres per litre) overstates helium contents by about 9–11 %, and even the ideal-gas figure overstates them by 7–10 %. A cylinder's contents are best stated in cubic metres at a named temperature and pressure, or by mass. The method, and the corrections for temperature, are worked through in gas laws and cylinder pressure.

Helium purity grades

Helium is sold by purity, written either as a percentage or in the N-notation used across the gas industry. The first digit is the number of nines; the digit after the point is the last figure.

Grade Minimum purity Total impurities, maximum Typical use
Balloon grade about 99 % about 1 % Party and display balloons
4.0 99.99 % 100 ppm General industrial, some welding
4.6 99.996 % 40 ppm Welding shielding gas, leak testing
5.0 99.999 % 10 ppm Leak testing, laboratory carrier gas, fibre optics
5.5 99.9995 % 5 ppm Analytical instruments
6.0 99.9999 % 1 ppm Semiconductor and research uses

The N-notation purities are definitions; the uses are typical practice. The Indian product standard is IS 15583, Compressed helium gas — Specification, issued in 2005 and revised in 2026; its grade limits are not quoted here, so ask for the grade by its stated purity and impurity limits. For any grade the certificate should list the impurities that matter for the job, typically moisture, oxygen, nitrogen and total hydrocarbons in ppm. The general system is set out in gas purity grades explained.

Liquid helium and MRI

Liquid helium boils at 4.22 K and has a density of only about 125 kg/m³, so one litre expands to roughly 750 litres of gas at 20 °C. Its main use is cooling the superconducting magnets of MRI scanners and NMR spectrometers, whose niobium-titanium windings superconduct only a few kelvin above absolute zero. A loss of superconductivity, called a quench, boils off a large part of the liquid very quickly, and the gas must be vented outside the building. Liquid helium is a cryogen as well as an asphyxiant; any surface at 4 K condenses air, and the liquid air that forms is enriched in oxygen. Helium does not freeze at atmospheric pressure at any temperature, which is one reason it is the coolant of choice for low-temperature physics.

Where helium comes from

Helium is recovered from certain natural-gas fields where radioactive decay has built it up to a fraction of a per cent or more. Air contains only about 5 ppm, too little to recover economically, so air separation plants do not produce it. India has no producing field, and all helium used in India is imported, as liquid in large vacuum-insulated containers or as compressed gas. KIGL does not produce helium; it supplies helium sourced from licensed producers through the helium gas page. Because the supply is finite and the price volatile, recovery and conservation matter, as discussed under helium supply and conservation.

Rules that matter

What this means for you

  • Specify helium by grade and impurity limits, not just "high purity"; 4.6 suits most welding, 5.0 most leak testing.
  • State contents in m³ at a named temperature, or by mass; 1 kg of helium is about 5.6 m³ at 0 °C.
  • Do not estimate contents from water capacity times pressure; helium's Z of about 1.07 at 150 bar means that overstates them.
  • Ventilate high, because helium rises; and never let anyone inhale it.
  • Check the middle brown cylinder and the stamped contents before connecting, and read the helium safety data sheet.

Helium technical data — frequently asked questions

Why is helium used in balloons instead of hydrogen?

Because helium cannot burn. At 0.169 kg/m³ at 15 °C it gives a lift of about 1 kg per cubic metre, which is why party, display and most advertising balloons use it. Hydrogen lifts slightly more but is flammable from 4 to 75 % in air, so it is unsuitable near people. Hot-air balloons use heated air. Never inhale balloon gas; it contains no oxygen.

What is the boiling point of helium?

−268.93 °C, or 4.22 K, at 1 atm (NIST), the lowest boiling point of any substance. Helium has no solid phase at atmospheric pressure. Its critical temperature, 5.2 K, is so low that helium is always a gas in a cylinder at any ambient temperature, however high the pressure, which is why it is sold compressed and never as a cylinder liquid.

What does helium 5.0 mean?

Helium 5.0 is at least 99.999 % helium, with total impurities no more than 10 ppm. The first digit counts the nines and the second gives the last digit, so 4.6 is 99.996 % and 6.0 is 99.9999 %. The grade states minimum purity; the certificate should also list the main impurities, normally moisture, oxygen, nitrogen and hydrocarbons, in ppm.

How much helium gas is in a cylinder?

At 150 bar and 15 °C, NIST gives a helium density of 23.35 kg/m³, so each litre of water capacity holds about 23 g, or about 138 litres of gas at 1 atm. Helium is less compressible than an ideal gas at that pressure (Z about 1.07), so water capacity times gauge pressure overstates the contents by about 9 %.

What is the density of liquid helium?

About 125 kg/m³ at its boiling point of 4.2 K (NIST), one-eighth of water. One litre of liquid gives roughly 750 litres of gas at 20 °C. Because its latent heat is very small, a dewar of liquid helium boils off quickly if insulation or vacuum is lost.

How cold is liquid helium compared with liquid nitrogen?

Liquid helium boils at −268.93 °C (4.22 K) and liquid nitrogen at about −195.8 °C (77 K), both at 1 atm (NIST), so liquid helium is some 73 degrees colder. A surface at liquid-helium temperature freezes nitrogen and oxygen solid and condenses air, which is why helium transfer lines are vacuum-jacketed and often shielded by a liquid-nitrogen jacket.

References

  1. Bureau of Indian Standards. (2021). Identification of the contents of industrial gas cylinders (IS 4379:2021, Second Revision).
  2. CGA helium publications, Compressed Gas Association
  3. EIGA safety information on inert gases and cryogenic liquids, European Industrial Gases Association
  4. Government of India. (2016). Gas Cylinders Rules, 2016 (G.S.R. 1081(E)). Petroleum and Explosives Safety Organisation.
  5. IS 15583 Compressed helium gas, Bureau of Indian Standards
  6. Linstrom, P. J., & Mallard, W. G. (Eds.). (n.d.). NIST Chemistry WebBook (NIST Standard Reference Database 69). National Institute of Standards and Technology. [Thermophysical properties of fluid systems, helium] https://webbook.nist.gov/cgi/cbook.cgi?ID=C7440597

Enquiries

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